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By spectral (UV-VIS, IR, NMR, MS and CD) methods the quinone antibiotics sarubicin A and U-58,431 were shown to have identical constitution and stereochemistry. Chiroptical data and their theoretical analysis have settled the common absolute configuration as 5S, 6R, 8R, 10R.


K Eckardt, D Tresselt, W Ihn, M Kajtár, J Angyán, L Radics, M Hollósi. Constitution and absolute stereochemistry of the antibiotic sarubicin A. The Journal of antibiotics. 1983 Aug;36(8):976-9

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PMID: 6630068

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