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The formation of two-dimensional halogen-bonded layers of 4,4'-bipyridyl and 1,4-diiodotetrafluorobenzene was observed on a graphite surface at sub-monolayer coverage using synchrotron X-ray diffraction; the use of the diffraction technique enabled, for the first time, the measurement of I···N halogen bonding distances in a two-dimensional cocrystal and the identification of the halogen bonding interaction in the monolayer.

Citation

Stuart M Clarke, Tomislav Friščić, William Jones, Anasuya Mandal, Chenguang Sun, Julia E Parker. Observation of a two-dimensional halogen-bonded cocrystal at sub-monolayer coverage using synchrotron X-ray diffraction. Chemical communications (Cambridge, England). 2011 Mar 7;47(9):2526-8


PMID: 21180747

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