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The secondary metabolites VM55599 (4) and preparaherquamide (5) have been identified by LC-MS(n) analysis as natural metabolites in cultures of Penicillium fellutanum, whereas preparaherquamide has been identified only in cultures of Aspergillus japonicus. In accord with a previous proposal, the identification of both metabolites, which have a diastereomeric relationship, provides indirect support for a unified biosynthetic scheme.


Yousong Ding, Sabine Gruschow, Thomas J Greshock, Jennifer M Finefield, David H Sherman, Robert M Williams. Detection of VM55599 and preparaherquamide from Aspergillus japonicus and Penicillium fellutanum: biosynthetic implications. Journal of natural products. 2008 Sep;71(9):1574-8

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PMID: 18754595

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