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structure: see text] The complete stereostructure of the natural product (+)-glisoprenin A had been predicted via a novel application of chiral lanthanide shift reagents. Confirmation of the predicted stereostructure of (+)-glisoprenin A and validation of the chiral lanthanide shift approach have now been achieved through total synthesis.


Christopher M Adams, Indranath Ghosh, Yoshito Kishi. Validation of lanthanide chiral shift reagents for determination of absolute configuration: total synthesis of glisoprenin A. Organic letters. 2004 Dec 9;6(25):4723-6

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PMID: 15575670

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