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Both the enantiomers as well as the racemate of 3-butyl-7-hydroxyphthalide (1) were synthesized, and the absolute configuration of the naturally occurring (-)-1 (a weakly cytotoxic metabolite of Penicillium vulpinum) was identified as S.


Tomoya Ohzeki, Kenji Mori. Synthesis and absolute configuration of (-)-3-butyl-7-hydroxyphthalide, a cytotoxic metabolite of Penicillium vulpinum. Bioscience, biotechnology, and biochemistry. 2003 Oct;67(10):2240-4

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PMID: 14586114

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